Can tiny compounds make our planet greener?

We know that human activity is having extreme adverse consequences for our planet and researchers are battling to find solutions. One of the most exciting fields to emerge is metal-organic frameworks (MOFs).

What are MOFs?

Discovered just over 20 years ago, MOFs represent one of today’s hottest fields of research. These ultra-highly-porous solids consist of metals like zinc or copper connected by ‘linkers’ of organic chemicals to form networks of empty pores almost like those in a kitchen sponge. However, these pores are much smaller than the diameter of a single human hair.

Up to 90% of a MOF consists of empty space that could be filled with hydrogen, carbon dioxide, medications for slow-release in the human body or a range of other materials. MOFs have such an enormous internal surface area - up to 7,000 square meters per gram - that a single ounce, unraveled and spread out, could cover the surface of 280 football fields.[1]

MOF的孔隙率是通过Susumu Kitagawa教授在1997年进行的一系列气体吸附实验发现的。Kitigawa最近收到了Emanuel Merck的讲座(EMLS)(EMLS)(EMLS)(EMLS),来自德国Darmstadt,德国和Darmstadt大学的默克KGAA,DARMSTADT的持续开放式工作。这个领域。[2]

Since their discovery, MOFs have attracted extensive and continually increasing interest from both academia and industry owing to their unprecedented porosity, structural and functional diversity. Proposed applications of MOFs include gas separation, gas storage, catalysis, and carbon capture, as well as in emerging medical technologies.[3]

DID YOU KNOW?

  • ≈1 oz

    A single ounce of a MOF, unraveled and spread out, could cover the surface of 280 football fields.

  • 90%

    of a MOF consists of empty space.

  • 7,000

    MOFs have an enormous internal surface area - up to 7,000 square meters per gram.

Applications of MOFs: clean energy and a greener planet

Our planet is in crisis. The impact of human activity has now reached a scale at which it interferes profoundly with Earth’s atmosphere, ice sheets, ocean, forests, land and biodiversity.[4]

Greenhouse gas emissions have risen at alarming rates and in April 2018, levels of carbon dioxide in the atmosphere reached an average of 410 parts per million (ppm) across the entire month – the highest level in at least 800,000 years.[5]

MOFs may be small, but we believe their impact on these issues could be huge. Their unique properties mean they show immense promise for tackling a range of environmental issues. Here are a couple of important examples:

Using metal-organic frameworks for carbon capture and cleaning the air

Given the alarming levels of carbon dioxide now present in our atmosphere, developing efficient carbon capture and storage techniques is vital.But carbon dioxide is not the only potentially problematic gas being released into our atmosphere. Globally, nearly 150 million tons of ammonia (NH3) are produced every year to be used in manufacturing fertilizers, pharmaceuticals, commercial cleaning products, refrigerants, and more. Meanwhile, sulphur dioxide and nitrogen oxides in flue gas are well-known for their damaging effects on the environment, causing the formation of haze and acid rain, as well as contributing to climate change.Their high porosity, variable pore size, and high concentrations of active adsorption sites make MOFs a promising class of materials for use in capturing many of these gases during industrial activity and production processes - making it far less likely they will pollute our atmosphere.

MOFs in clean energy production and storage

MOFs also have a role to play in promoting the use of cleaner fuels. For example, oxyfuel combustion requires the delivery of oxygen rather than air to a combustion chamber, so that the gaseous product of the reaction is near-pure carbon dioxide, rather than a mix of gases. The advantage of this is that no separation of gases is required for carbon capture. However, widespread implementation of oxyfuel combustion technology requires industrial-scale quantities of high purity O2。目前,生产此产品的过程既昂贵又耗能,但是金属有机框架有可能改变这种状况。其他有希望的可再生燃料 - 氢(H2) and methane (CH4) - stand poised to offer cleaner, greener alternatives to gasoline for powering motor vehicles. However, it has so far been impossible to store these gases at a high enough capacity to enable their widespread adoption. MOFs are the most promising materials for achieving the hydrogen and methane storage capacities needed to make them viable alternatives to current fuels.

The future of MOFs

The numerous advantages of MOFs, particularly their high surface area and modular composition, place them at a multidisciplinary crossroads. For good reason, MOFs are one of the most active research fields today, with aspects of their fundamental and applied properties permeating into disciplines as varied as electronics, medicine, chemical engineering, and optics. They have the potential to make significant contributions to everything from fighting climate change to beating cancer. It feels highly appropriate, given their composition, to say ‘watch this space’!

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  • Gina Guerrero Feb 08 2021, 11:52 PM

    Good day! And hello Collegues! Yes, I work at MilliporeSigma. I was looking through Linked In and happened across the article on MOFs. I have a keen interest in environmental issues. In fact just this past year I received my BS in Environmental Science specializing in Land Resource Management. I was reading how MOFs could be used to capture CO2 and other aerosolized pollutants. I live in a farming community and it is common for our watershed to test high in various chemicals and pesticides due to runoff from the farms. Can MOFs also be used to capture chemical pollutants in the soil? Or even pollutants in rivers, lakes, or oceans? I understand that absorption of pollutants in our waterways might be challenging because MOFs might actually capture water instead. But is it possible to tailor the MOF to absorb specific chemicals? How fascinating! Thank you for your time. Gina guerrero

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